Tris(hydroxymethyl)methanaminium trifluoroacetate
نویسنده
چکیده
In the crystal structure of the title salt, C(4)H(12)NO(3) (+)·C(2)F(3)O(2) (-), N-H⋯O and O-H⋯O hydrogen bonds link the ions, forming a complex three-dimensional network.
منابع مشابه
Tris(pyridin-2-ylmethanol)nickel(II) hexafluoridophosphate trifluoroacetate
In the crystal structure of the title complex, [Ni(C(6)H(7)NO)(3)](PF(6))(C(2)F(3)O(2)), the Ni(II) ion is in a slightly distorted octa-hedral NiO(3)N(3) coordination geometry with each of the three N and three O atoms in a meridional coordination. In the crystal, the complex mol-ecules and the trifluoro-acetate anions are connected via O-H⋯O hydrogen bonding into layers parallel to the ab plane.
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In the title complex, [Cu(H(2)NCH(2)CH(2)NH(2))(3)](CF(3)COO)(2), the environment of the Cu atom is distorted octa-hedral, formed by six N atoms from three chelating ethane-1,2-diamine ligands. The Cu-N distances range from 2.050 (2) to 2.300 (2) Å. This complex cation and the two trifluoro-acetate anions are connected by weak N-H⋯O and N-H⋯F hydrogen bonds, forming a three-dimensional framewor...
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The asymmetric unit of the title compound, 2C13H14N2O3·C3H10NO3 (+)·Cl(-), contains two independent mol-ecules (A and B) of the title pyrimidine derivative and one ion-pair of tris-(hy-droxy-meth-yl)ammonium chloride. The pyrimidine ring in each pyrimidine derivative has a half-chair conformation. Its mean plane is inclined to the benzene ring by 87.2 (3)° in mol-ecule A and 85.7 (2)° in mol-ec...
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The asymmetric unit of the title structure, [CoCl2(C3H11NOP)4][CoCl4]2, consists of one half of the trans-dichlorido-tetra-kis-[(di-methyl-phosphor-yl)methanaminium]cobalt(II) tetra-cation lying on an inversion center and one tetra-chloridocobaltate(II) dianion on a general position. Four O-coordinated cationic (di-methyl-phosphor-yl)methanaminium (dpmaH(+)) ligands occupy the equatorial coordi...
متن کامل(Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1)
The asymmetric unit of the title structure, C3H11NOP(+)·I(-)·C3H10NOP, consists of one (di-methyl-phosphor-yl)methanamine (dpma) mol-ecule, one (di-methyl-phosphor-yl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium-strong to weak N-H⋯O and N-H⋯N hydrogen bonds connect dpmaH cations and dpma mol-ecules into strands along [001]. The iodide counter-anions form only v...
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